Water-wettable drilling mud additives containing uintaite

ABSTRACT

A water-based drilling mud additive comprising a preblended combination of about 2 parts of high softening point uintaite, about 1 part of a lower softening point uintaite, about 1 part of causticized lignite, and a strongly lipophilic, non-ionic surfactant is disclosed. This composition decreases shale sloughing and bore-hole instability during drilling of wells.

FIELD OF THE INVENTION

This invention relates to a new composition of matter which is useful inwater-based drilling fluids. More particularly, this invention relatesto a drilling mud additive composition comprising two uintaites ofdifferent softening points, causticized lignite and a highly lipophilicnon-ionic surfactant.

BACKGROUND OF THE INVENTION

Uintaite is a naturally occurring hydrocarbon mineral classified as anasphaltite. It is a natural product whose chemical and physicalproperties vary and depend strongly on the uintaite source. Uintaite hasalso been called `gilsonite` although this usage is incorrect;Gilsonite® is a registered trademark of American Gilsonite Co., SaltLake City, Utah. American Gilsonite Co sells a variety of Gilsonite®`resins`, sometimes identified by their softening points (ring andball). For example, General Purpose (GP) Gilsonite® brand resin has asoftening point of about 350° F, and Gilsonite® HM has a softening pointof about 380° F, and Gilsonite® Select 300 and Select 325 which havesoftening points of about 300 and 325° F, respectively. The softeningpoints of these natural uintaites depend primarily on the source veinthat is mined when the mineral is produced. Uintaite is described in theKirk-Othmer Encyclopedia of Chemical Technology, 3rd Ed. Vol. 11, 198C,pp. 802-806, which is incorporated herein by reference. Typical uintaiteused in drilling fluids is mined from an area around Bonanza, Utah andhas a specific gravity of 1.05 with a softening point ranging from 370°F to 400° F, although a lower softening point (330° F) material issometimes used. It has a low acid value, a zero iodine number, and issoluble or partially soluble in aromatic and aliphatic hydrocarbons,respectively. It is generally processed and ground to where 99% passesthrough a 65-mesh Tyler screen with approximately 3% being retained on a100-mesh screen and 16% on a 200-mesh screen, non-cumulative.

For many years uintaite and other asphaltic-type products have been usedin water-based drilling fluids as additives assisting in boreholestabilization. These additives can minimize hole collapse in formationscontaining water-sensitive, sloughing shales. See, for example, SPEPaper 17203 (1988) to Davis and Tooman which is incorporated herein byreference in its entirety.

The causes of borehole instability are numerous. They can be mechanical,chemical, or physical in nature. Mechanical problems include boreholeerosion by high annular velocities, adverse hydraulic stresses due tohigh annular pressures, hole collapse from high swab and surge pressuresdue to excessive wall cake, and stressed erosion due to drill stringmovement. Chemical alteration problems include hydration, dispersion,and disintegration of shales due to the interaction of clays with mudfiltrate.

Physical instability problems include the spalling and rock bunts ofshales due to in-situ rock stress and the difference between mudhydrostatic and formation pressures. Fracture and slippage along beddingplanes of hard, brittle shales, and the collapse of fractured shalesabove deviated holes are also physical problems encountered whiledrilling troublesome shales.

Borehole instability problems are often referred to as sloughing,heaving, spalling, or overpressured shales, mud balls, mud rings, andmany other descriptive names. There are many solutions to this problem.For example, additives have been used to inhibit or partially inhibitthe swelling of clay. The adjustment of hydraulic conditions is anothersolution to reduce mechanical alteration. Knowing and controlling thepore pressure of the problem formations is used often.

Uintaite and asphalt-type materials have teen used for many years tostabilize sloughing shales and to reduce borehole erosion. Otherbenefits derived from these products include borehole lubrication andreduction in filtration. Numerous patents and publications disclosedrilling mud additives containing uintaite.

Canadian Patent 972,141 to Sullivan discloses a well drilling fluidcontaining ground particles of uintaite (gilsonite) pre-coated with anon-ionic surfactant to make the particles water-wettable. Preferredsurfactants are phosphate esters-derived from the group consisting ofpolyoxyethylene ethers of organic compounds containing at least 6 carbonatoms and having a reactive hydrogen and condensed with at least 3 molsof ethylene oxide. A process for using this composition in well drillingoperation is also disclosed.

U.S. Pat. No. 4,645,609 to Patel discloses mixtures of causticizedlignite and sulfonated asphalts, including uintaite (gilsonite), aswell-working fluids. U.S. Pat. No. 4,420,405 to McCrary disclosescompositions and their methods of preparation comprising uintaite(gilsonite), lignite, tannin and a sulfonating compound, preferablysodium sulfite, as drilling mud additives.

U.S. Pat. No. 3,718,585 to Lummus et al. discloses an aqueous drillingfluid consisting of uintaite (gilsonite), a stabilizing agent and analcohol. The stabilizing agent is a particular ethoxylated alkylphenolor a polypropylene glycol (Mw between 1700 and 3500) reacted with 8 to13 wt. % ethylene oxide. The stabilizing agent is prehydrated to assistin dissolution and to prevent gum formation.

Although the above-described patents teach many improvements, a numberof problems still exist when using uintaite-containing drilling fluidadditives. Of particular importance is that no one additive is usefulfor the entire range of temperatures and pressures downhole.

Also, uintaite is not easily water wet with most surfactants. Thus,stable dispersions of uintaite are often difficult to achieve,particularly in the presence of salts, calcium, solids and otherdrilling fluid contaminants and/or in the presence of diesel oil. Theuintaite must be readily dispersible and must remain water wet;otherwise it will coalesce and be separated from the drilling fluid,along with cuttings at the shale shaker or in the circulating pits.

Surfactants and emulsifiers are often used with uintaite drilling mudadditives. Surfactant-coated uintaite powders are also known. However,the surfactant of the surfactant-coated uintaite powders can lose itseffectiveness over time, thereby causing stickiness or aggloxeration ofthe uintaite particles. Alternatively, the surfactant may evaporateleaving unwettable uintaite. Ideally the surfactant-coated uintaiteshould be storage stable for extended periods of time, withoutdeterioration of performance.

Another serious problem with drilling mud additives is that they can bevery sensitive to diesel fuel addition or contamination, resulting inkickout of the additive. Diesel kickout results in loss of the additiveor the collecting screens.

Borehole stability tests of uintaite and other asphaltic-type additiveshave been conducted at ambient temperatures and pressures for manyyears. However, prediction of additive performance under downholeconditions has been unreliable. Borehole temperatures can vary fromambient up to 500° F and pressures can vary from atmospheric up to25,000 psi. Only recently have tests beer devised under simulateddownhole conditions. The Downhole Simulation Cell (DSC) described in theSPE Paper 17202 by Simpson, Dearing, and Salisbury is one example ofthese new tests. Another is described in the paper of Davis & Tooman,SPE Paper 17203 which used a High Pressure/Hi9h Temperature Fluid Losscell and Berea cores to determine the depth of intrusion of drilling mudadditives into the Berea core. This paper compared commerciallyavailable uintaite and asphaltic additives under downhole conditions.Using these new test procedures, we have now developed additives withsignificantly improved performance.

It would be advantageous if a uintaite drilling mud additive compositioncould be provided that was water-wettable and could be rewet rapidly,that would be effective over a wide range of temperatures and pressures,that would have improved stability to diesel fuel contaminants indrilling wells, and that would be storage stable, maintaining rapidwettability over time.

It would be advantageous if a single uintaite drilling mud additivecomposition could be provided that was effective in preventing shalesloughing and minimizing borehole instability over a broad range oftemperatures, such as those encountered from spud to total depth (TD),and did not require surfactant addition at the drill site.

One object of the present invention is to provide a composition that isuseful in water-based drilling fluids to prevent shale sloughing.

Further objects of the invention will become evident to those skilled inthe art by reading the following specification, including the examplesand the claims.

SUMMARY OF THE INVENTION

The present invention is a composition useful in water-based drillingfluids. In one embodiment the composition is a water-wettable drillingmud additive that stabilizes a borehole during well drilling, comprisinga pre-blended stabilizing combination of a high softening pointuintaite, a lower softening point uintaite, causticized lignite, and astrongly lipophilic non-ionic surfactant.

In a preferred embodiment, the composition comprises a mixture of:

a) 45 to 55 percent of a uintaite having a softening point of about 375°F.;

b) 20 to 30 percent of a uintaite having a softening point of about 325°F.;

c) 20 to 30 percent of causticized lignite; and

d) 2 to 4 percent a non-ionic surfactant which comprises a blockcopolymer of ethylene oxide and propylene oxide, and provides arewetting index of less than about 2 to the uintaites.

In another aspect, the present invention is a method of stabilizing anoil well to shale sloughing using the instant drilling fluid additivecomposition. In another embodiment, the invention is a method ofdrilling a well, comprising the steps of inserting a drill bit into thewell and circulating a drilling mud comprising the additive describedabove.

Among other factors we have unexpectedly found that a compositioncomprising a mixture of two different uintaites, one of which has asoftening point above about 325° F and the other having a softeningpoint of about 375° F, causticized lignite and a highly lipophilicsurfactant-when combined in the proper ratio-produces a water-wettabledrilling mud additive that stays water wettable and is extremelyeffective over a wide range of wellbore temperatures.

DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS OF THE INVENTION

We have now discovered a uintaite-containing drilling mud additive thatis particularly effective in minimizing borehole enlargement andcontrolling sloughing shale problems over a wide temperature range. Thiscomposition is a unique combination or mixture of a strongly lipophilicnon-ionic surfactant, causticized lignite and at least two uintaiteshaving different softening points. We have found that an additivecomprising this combination in effective stabilizing amounts results insignificantly improved performance over a wide range of welltemperatures, such as from ambient temperatures to 250° F and higher.Typically, these additives may be used at temperatures up to about 400°F.

Using a mixture of uintaites having softening points at least 40° Fapart or more, preferably about 50° F apart, is critical to thisinvention. We have discovered that this mixture of uintaites increasesthe range of temperatures over which the additive is useful.Additionally, we have found that inclusion of causticized lignite isnecessary for good performance at high temperatures, such as250° F.Moreover, the surfactants described below are critical to dispersing theuintaites into the drilling mud and keeping them wetted.

In one aspect, our invention is a water-wettable drilling mud additivethat stabilizes a borehole during well drilling, comprising apre-blended borehole stabilizing combination of a high softening pointuintaite, a low softening point uintaite, causticized lignite, and astrongly lipophilic non-ionic surfactant. The surfactant provides theuintaite with a rewetting index of less than about 4, preferably lessthan about 2.

In a preferred embodiment, the water-wettable drilling mud additive ofour invention comprises a mixture of:

a) 45 to 55 percent of a uintaite having a softening point of about 375°F.;

20 to 30 percent of a uintaite having a softening point of about 325°F.;

c) 20 to 30 percent of causticized lignite; and

d) 1 to 5 percent a non-ionic surfactant which comprises a blockcopolymer of ethylene oxide and propylene oxide, and provides a wettingindex of less than about 2 to the uintaites.

The additive of this invention is a pre-blended mixture, that is, it isa single, solid component that is already pre-mixed when sold for usedownhole. It does not require additional surfactants and emulsifiers atthe drill site. The additive composition of the invention can stabilizea borehole over the broad range of temperatures encountered in drillingwells.

Each of the components of this additive composition will now bedescribed.

The Uintaite Components

Uintaite is a naturally occurring asphaltic hydrocarbon ore. Uintaitesuseful in this invention have a broad range of softening points,typically between 300 and 400° F. Uintaite is the preferred asphalticmaterial in this invention. However, it is contemplated that otherasphaltic materials with softening points in this range could beeffective; for example, blown asphalt may be used to replace some or allof the low softening point uintaite.

Softening points of uintaite generally depend on the source or veinwhere the uintaite is mined. Preferably, the high softening pointuintaite has a softening point of at least 360° F., preferably 375° F.,or higher. Preferred high softening point uintaite has a softening pointof from about 370 to 390° F. Preferably, the lower or low softeningpoint uintaite has a softening point of about 330° F, or lower.Preferred low softening point uintaite has a softening point of from290-330° F., preferably about 325° F. The softening points of the twouintaites are preferably at least 40° F. apart, more preferably about50° F. apart or more.

It is contemplated that upgraded uintaite could be used to replace orpartially replace the low softening point uintaite. Uintaite can beupgraded by solvent extraction or precipitate to give lower softeningpoint products.

Using high temperature, high pressure testing equipment, we have foundthat the low softening point uintaite is effective in minimizingborehole instability during the early stages of the well where lowertemperatures, typically up to about 125°-175° F., are encountered. Wehave surprisingly found that at least about 20% of this low softeningpoint uintaite is necessary in the additive formulation to have good lowtemperature performance.

We have found that the high softening point uintaite is effective inminimizing borehole instability at higher well temperatures, such as180°-250° F. and higher. However, we have also found that it is criticalto combine causticized lignite with the uintaite mixture to obtain goodhigh temperature results.

Preferred weight ratios of the high softening point uintaite to thelower or low softening point uintaite are in the range of 4:1 to 1:2,more preferably in the range of 3:1 to 1:1, and most preferably about2:1.

In a preferred embodiment, the mixture of uintaites is made up of abouta 2:1 mixture of Gilsonite® HM, having a softening point of about 380°F, and Gilsonite® Select, having a softening point of about 325° F.Preferably, the ratio of Gilsonite® HM to Gilsonite® Select to ligniteis about 2 to about 1 to about 1.

The Causticized Lignite Component

Causticized lignite is well known in the art. It is prepared fromlignite, which is a variety of coal intermediate between peat andbituminous coal, by reaction with base, such as sodium or potassiumhydroxide. The lignite is causticized, i.e., reacted with base, becausethe causticized material is readily water-soluble. Causticized ligniteis commercially available and can be prepared in a manner known in theart. Suitable methods of causticizing lignite include those disclosed inU.S. Pat. No. 3,441,504 to Browning and U.S. Pat. No. 4,645,609 toPatel, the disclosures of which are hereby incorporated by reference. Apreferred lignite that may be causticized and used in this invention hasan oxygen content of at least about 20 weight percent, usually in therange of from about 20 to about 40 weight percent, measured on a drybasis. Lignitic materials which are high in humic acids, thus readilysoluble in basic solution, are most preferred. Presently preferred isLeonardite, which is characterized by its high oxygen content andincreased alkali solubility. Leonardite is a soft, earthy, medium brown,coal-like substance associated with lignitic outcrops in North Dakota,South Dakota, Montana and Texas, and is mined commercially. Normallignite may be converted to a material of similar properties toLeonardite by oxidation; such converted lignite may be used to preparecompositions of this invention. Leonardite has an oxygen content higherthan other types of lignite, generally about 28-29 percent oxygen,compared to 10 percent in lignite. This higher oxygen content is due tothe larger number of carboxylic acid groups, which may explain theimproved in alkali solubility of Leonardite as compared to otherlignites. Typical solubility of conventional lignite is about 68 weightpercent in alkali, whereas Leonardite has a solubility of about 85weight percent.

Causticized lignite is a component of many drilling muds. However, ourexperiments indicate that the causticized lignite must be pre-blendedinto the additive to achieve good high temperature (e.g., 250° F)borehole stabilization and improve the disperability of uintaite. It isadvantageous to uniformly blend the lignite into the additivecomposition.

The causticized lignite used in this invention is a solid. The weightratio of uintaites to causticized lignite in the instant pre-blendedadditive is preferably within the range of about 4:1 to 2:1, preferablyabout 3:1. The amount of lignite is preferably about equal to the amountof low softening point uintaite. The amount of lignite is alsopreferably about equal to twice the amount of high softening pointuintaite. Most preferably, the ratio of high softening point uintaite tolow softening point uintaite to lignite is 2 to 1 to 1.

The Surfactant Component

It is advantageous that uintaite be pretreated with surfactant prior toaddition to the drilling mud system. This results in the uintaite beingmore completely water-wet, and therefore more evenly dispersedthroughout the circulating system. The additive is in a more convenientand easier to use form.

The surfactant component of this invention is also critical. Thesurfactant must impart properties to the uintaite that result in adrilling mud additive that is effective in bore-hole stabilization overa wide temperature range.

The surfactant-treated or surfactant-coated uintaites useful in thisinvention must meet the following three wetting criteria. They musthave:

a) rapid initial wettability;

b) good rewettability after soaking in water; and

c) good wettability after storage for at least 30 days at 110° F., i.e.,they must be storage stable.

Additionally, the surfactant must perform well when mixed with drillingmud chemicals. Preferably, the surfactant should also have a flash pointabove 300° F. in order to avoid the possibility of ignition, and a pourpoint below 32° F. for ease of application to the uintaite. Preferably,the surfactant-treated uintaites should show good diesel resistance,i.e., they should not coalesce in the presence of 3% diesel.

These properties of the surfactant-treated uintaite are all dependent onthe surfactant chosen. Tests for these properties are described in theexamples.

Uintaite is not water-wettable. Loose or poor bonding of the surfactantto the uintaite will lead to its washing off during use, possibleagglomeration, and the removal of uintaite from the mud system with thedrilling wastes. Thus, the importance of the wettability, rewettability,and storage stability criteria is evident. It is especially important tochoose a surfactant that bonds or complexes tightly with the uintaites,but does not dissolve, soften or make the uintaite sticky as theresulting-additive should be free-flowing. Moreover, the surfactantshould not interact deleteriously with the causticized lignite, forexample by hindering its dissolution.

We have now discovered that the surfactant-treated uintaite useful inthis invention must have a Rewetting Index (RI) of less than about 4,preferably less than about 2, and most preferably about one. Usefulsurfactants must provide or impart this rewetting index to the uintaite.The RI is a good predictor of continuing uintaite dispersability duringuse in drilling.

The RI is determined by measuring the time it (initially) takes to wet asurfactant-treated sample of uintaite and the time it takes to rewet thesample after stirring with water and drying; Examples 2 and 4, below,discuss the details of how these tests are performed. The RI is theratio of the rewetting time to the initial wetting time, i.e., ##EQU1##Surfactants useful in this invention generally provide the uintaite withinitial wetting times that are less than about 10 seconds and rewettingtimes that are less than about 4 times the initial wetting times, andtherefore are less than about 40 seconds. More preferably, the ratio ofthe rewetting time to the initial wetting time is less than about 2 andmost preferably about 1.

Surfactant-treated uintaites that do not meet the RI criteria of lessthan about 4 tend to have surfactants that come off the uintaite inwater. These surfactants wash off the uintaite in the hot circulatingdrilling mud, resulting in loss of the uintaite from the mud systemthrough separation and lack of redispersion.

Preferred surfactants are highly lipophilic non-ionic surfactants. Bythe term `highly lipophilic` surfactant is meant a surfactant that has astrong affinity for a hydrocarbon phase, rather than water. In thesesurfactants, the relative contribution of the non-polar lipophilic tailto the polar hydrophilic head is high. Preferred surfactants have atleast 80% of their molecular weight in the hydro-phobic or lipophilictail, preferably about 90% or more.

Broadly speaking, preferred surfactants useful in this invention have ahydrophile-lipophile balance (HLB) value below about 3, preferably aslow as 1. Materials with low HLB values are especially useful in makingwater-in-oil emulsions. Surfactants with HLB values of 1-4 generallyhave poor to no dispersibility in water. HLB values are described in`Non-ionic Surfactants` (1967) edited by M. J. Schick, pp. 604-608,which is incorporated herein by reference, and in `Surfactants inSolution`, Vol. 3, edited by K. L. Mittal & B. Lindman (1984) pp.1928-1930, which is also incorporated herein by reference. It appearsfrom our experiments that the molecular weight of the surfactant is alsoimportant in providing low RI values.

Non-ionic surfactants having HLB values below about 3 include highmolecular weight fatty alcohols, such as cholesterol and lanolinalcohols; ethoxylated polyoxypropylene glycols, such as Alkatronic PGP33-1 and PGP 18-1; ethoxylated amines, such as those sold by TomahProducts Inc.; block copolymers of propylene oxide and ethylene oxide,such as those in the Tetronic series; and ethoxylated ethylene diaminepolyoxypropylene compounds, such as Alkatronic EDP 38-1 and EDP 28-1.Mixtures of surfactants are also envisioned.

An especially preferred surfactant is Pluronic L-101 which is anon-ionic surfactant manufactured by BASF-Wyandotte. It is a blockcopolymer surfactant comprised of 10 wt. % ethylene oxide and 90 wt. %propylene oxide, and is terminated with the ethylene oxide groups andwith primary hydroxyl groups. Pluronic L-101 has an HLB value of 1 andis strongly lipophilic. Its average molecular weight is about 3800, itsviscosity is 800 cps at 25° C., and its pour point is -23° C.

We have compared Plutonic L-101 with its sister surfactants PluronicL-61 and L-81 (see Table II below). These sister surfactants havesimilar structures to Pluronic L-101, i.e., they are block copolymersurfactants with 10 wt. % ethylene oxide and 90 wt. % propylene oxide.However, these sister surfactants have lower molecular weights, 2000 and2700 respectively, and do not provide an RI of less than 4 to theuintaite. It appears that the RI is affected by surfactant molecularweight as well as HLB.

The Drilling Mud Additive Composition

In one aspect, the present invention is a pre-blended mixture of a highsoftening point uintaite, a low softening point uintaite, causticizedlignite, and a surfactant that provides the uintaites with a rewettingindex of less than about 4. This borehole stabilizing combination ofcomponents is combined in amounts or ratios such that the combinationstabilizes the borehole at both low (ambient to 175° F.) and high(180-450° F., especially 180-350° F) borehole temperatures.

The drilling mud additive of this invention is a preblended,free-flowing solid or powder. Preferred amounts of the above describedcomponents in the additive are:

    ______________________________________                     Preferred  Most Preferred    Component        Range, %   Range, %    ______________________________________    High softening point uintaite                     30-70      45-55    Low softening point uintaite                     15-40      20-30    Causticized lignite                     15-40      20-30    Lipophilic surfactant                     0.1-10     1-5    ______________________________________

wherein said percents are by weight. The surfactant is preferablyapplied evenly to the surface of the uintaite.

An especially preferred product comprises about 2 parts Gilsonite® HM,about 1 part Gilsonite® Select, about 1 part causticized lignite andabout 0.1 to 0.15 parts of a non-ionic surfactant which imparts arewetting index of less than about 2 to the uintaite; an especiallypreferred surfactant is Pluronic L-101.

Preparation of the Additive of this Invention

In one aspect, the present invention is a method of preparing awater-wettable drilling mud additive comprising the steps of: mixingtogether a high softening point uintaite solid and a low softening pointuintaite solid, pulverizing said solids and adding causticized ligniteand a strongly lipophilic surfactant. Preferably, the surfactant is anon-ionic surfactant that provides the uintaite with an RI of less than4, preferably less than about 2.

In a preferred embodiment, the drilling mud additive composition of thisinvention can be prepared by mixing together the uintaite solids,pulverizing this mixture of solids, adding the causticized lignite andadding the surfactant. The lignite may be added prior to, during, orafter the surfactant is added. It is advantageous to grind or pulverizethe solids so that they are a fine powder, such as -200 mesh (Tylersieves).

The surfactant is preferably added to this mixture by spraying, althoughother methods may be used. It is advantageous to evenly apply thesurfactant to the surface of the uintaite so that wetting in use will berapid and complete. Alternatively, the surfactant can the dissolved ortrapped in the uintaite, for example, it can the combined with moltenuintaite, which is then solidified and pulverized.

The causticized lignite can be added during pulverization and prior toaddition of the surfactant; or it can be added after the surfactant isadded; or both lignite and surfactant can be added simultaneously. It ispreferred that the causticized lignite be added during pulverization andconcurrent with the surfactant.

Preferably the uintaite powders are mixed at ambient temperatures andpressures, the pulverization is accomplished in an impact mill, and thesurfactant is evenly distributed onto the solids, for example, byspraying. The resulting pre-blended additives do not require additionalsurfactants or emulsifiers when used in the field, although they can beused.

Using the Drilling Mud Additive

The additive of this invention can be used to decrease shale sloughingand borehole instability in any water-based drilling mud or drillingfluid. Preferably the additive is used in organic or polymer-baseddrilling muds. These drilling muds are commonly used in the industry andtypically comprise mixtures of polymers, clays, weighting agents,organic thinners, salts, starches, other chemical treating agents, andsometimes diesel oil.

This additive is also especially useful with chromelignosulfonate/lignite or polymer muds. These muds are well known in theart. Typical polymer components used in drilling muds include partiallyhydrolyzed polyacrylamides, polyanionic celluloses and polyacrylates toname a few. The additive can be added directly to the water-baseddrilling muds and may be dispersed without use of an emulsifier.

In one embodiment, this invention is a method of drilling a well,comprising the steps of inserting a drill bit into the well andcirculating a drilling mud containing the additive of this invention asdescribed above. The additive is useful over a broad range oftemperatures from ambient to 400° F., preferably from ambient to 300° F.In use, application rates can range from 1 to 10 lbs. of this additivecomposition per barrel of drilling fluid, preferably 2 to 6 lbs. areused.

The additives of this invention stabilize sloughing shales and reduceborehole erosion. Other benefits include bore-hole lubrication and areduction of high temperature/high pressure filtration.

Although not intended to be limited by any theory, it is believed thatthese additives minimize borehole instability due to physical alterationand, to some extent, chemical alteration. They help reduce sloughingshale problems by minimizing shale slippage along microfractures orbedding planes by physically sealing and plugging these cracks. Thus, itis believed that these additives when added to a mud system prior toencountering a problem shale, penetrate the shale pore spaces,microfractures, and bedding planes as the bit is penetrating theformation. By a plastic-flow mechanism, the uintaites extrude into thepores, fractures, and bedding planes to reduce or minimize filtrate andwhole mud invasion, and thus bond the matrix to prevent sloughing. Inaddition, uintaite may plate out on the borehole wall, creating a thinfilm.

The combination of two, or more, uintaites having somewhat differentplastic-flow properties results in a broader useful temperature range.The softening point of the uintaite, the temperature and the pressureall influence the depth of invasion of the uintaite. It is desirable toobtain some intrusion, but not a deep depth. The desirable depth ofintrusion should be shallow, around one millimeter. The lower softeningpoint uintaite plugs effectively with shallow intrusion (<1 mm) at lowertemperatures (150° F.). At higher temperatures (300° F.), the lowertemperature softening point uintaite intrudes deeper than the desirabledepth while the higher softening point uintaite intrudes to thedesirable depth. A blend of high temperature and low temperaturesoftening point uintaites have tested to be effective over a broad rangeof temperatures (150°-300° F.).

The surfactant, which imparts a Rewetting Index of less than about 4,preferably less than about 2 to the uintaite is critical to keeping theuintaite water-wettable. These surfactants bind strongly to theuintaites and provide good surface wetting characteristics. Moreover,these surfactants stay bound to the uintaite even within the drillingmud, which contains water, large amounts of clays, contaminants,formation solids, weighting materials, chemical additives and dieseloil. Also, these surfactants appear to have a low affinity for rock,especially relative to their affinity for uintaite. It is believed thatthe surfactant and the causticized lignite are both needed to aid indispersing the uintaite into the drilling mud.

The invention will be better understood in light of the followingspecific examples, which are merely illustrative and should not beconstrued as limiting the invention in any respect, as will be evidentto those skilled in the art

EXAMPLES EXAMPLE 1

Preparing Surfactant-Coated Uintaite A wide range of surfactants weretested for use in this invention. The surfactants were added topulverize Gilsonite® HM brand uintaite by use of a v blender equippedwith a liquid dispersion bar at room temperature, resulting inevenly-coated uintaite. The Gilsonite® HM was ground to meet Criteria Aof Example 11. The weight percent surfactant was either 3 or 5% of theuintaite.

Example 2 Dynamic Wettability Test-Initial Wetting

Two hundred (200) mi tap water at 77° F in a 400-ml beaker was stirredat full vortex with a 2-inch long magnetic bar. Three (3) grams of asurfactant-treated uintaite of Example 1 was added. Results werereported as the time (seconds) taken to wet the entire sample. Theendpoint, at which the entire sample was wet, can be determined byvisual inspection. When the uintaite was wet, its appearance changed. Itdarkened and was totally submerged in water. When the uintaite did notwet, the material continued to float on the surface. To pass this test,the time to complete wetting was 10 seconds or less. This 10-secondcriteria has been found to correlate well with good mixing and wettingperformance in the field. Samples were generally run in duplicate, withresults agreeing within 1-2 seconds.

EXAMPLE 3 Storage Stability Test

The surfactant-treated samples of Example 1 were tested using theprocedure in Example 2. A second portion of these samples was stored at110° F for 30 days in a brown paper lunch bag. The procedure of Example2 was repeated on these stored samples. A wetting time of less than fourtimes the original wetting time was considered a pass.

EXAMPLE 4 Rewetting Test

To 800 ml tap water at 77° F was added 20 grams of surfactant-treateduintaite of Example 1. This mixture was stirred at full vortex with a2-inch long magnetic stir bar for 10 minutes, then poured through a1.5-micron filter. The filtered solids were dried for 24 hours at 110°F. and passed through a 65-mesh screen. The dynamic wettability test ofExample 2 was run on this water-treated uintaite sample. To pass thistest, the wet

ting time had to be less than four times the original wetting time,preferably the rewetting time was less than two times the originalwetting time.

EXAMPLE 5 Preparation of a Base Mud

A base drilling mud was prepared by mixing 18.0 pounds/barrel bentoniteclay, 0.5 pounds/barrel sodium hydroxide, 2.0 pounds/barrel chromelignosulfonate in one barrel of distilled water. This base mud was usedto test the diesel fuel resistance of the surfactant-treated uintaites.

EXAMPLE 6 Diesel Fuel Resistance of Additives

This test was used to determine diesel fuel resistance of variousdrilling mud additives. Three hundred fifty (350) milliliters of basemud of Example 5 was heated to 150° F. in a 800-milliliter beaker whilestirring at 500 revolutions per minute using a 154-inch Kaufmandispersion blade. Six grams of the additive was added to the beakerwhile stirring. Stirring was continued for thirty minutes, at which timethe below-indicated amount of diesel fuel was added with continuousstirring for an additional sixty minutes. The beaker was removed fromstirring and allowed to cool, covered, for sixty minutes. The sample wasreheated to 150° F. and stored for 60 minutes. The beaker was removedfrom heat and immediately poured through a 65-mesh Tyler sieve. Thesieve was air dried, photographed and weighed to evaluate the amount of65-mesh retains. Two commercially available uintaite additives, X and Y,were tested and compared with the additive of this invention.

                  TABLE I    ______________________________________    Weight retained on Sieve.sup.(1)                     1% Diesel                             3% Diesel    ______________________________________    Additive X         7.8       13.4    Additive Y         7.7       11.9    Gilsonite ® HM + Pluronic                       4.2       7.4    L-101    Product from Example 10                       3.9       4.9    ______________________________________     .sup.(1) Weight in grams on Tyler 65mesh sieve.

The lower the weight retained on the sieve, the less product was kickedout by the added diesel, and therefore, the better the additive. As canbe seen, the additive of this invention had lower solids kicked out thanother tested additives, including other commercially available mudadditives containing uintaite, i.e., additives X and Y. The good dieselresistance of our additive is an advantage. For screening purposes, avisual inspection at 3% diesel was used. The surfactant-treateduintaites of Example 1 were mixed with the drilling mud at 150° F andstirred for 1/2 hour. Then 3 % diesel was added. Total separation in thepresence of the added diesel was a failure.

EXAMPLE 7 Flash Point Measurement

Flash points were measured using ASTM Method D-92-78. The flash point ofthe surfactant needs to be >300° F., so that the pulverization of theadditive components can be accomplished safely.

EXAMPLE 8 Softening Point of Uintaite

The softening point of the uintaites is measured by ASTM MethodE-28-51T. It is a ring and ball softening point.

EXAMPLE 9 Results from Surfactant Testing Experiments

Surfactant-treated uintaites as prepared in Example 1 were tested usingthe tests described in Examples 2-7. The results are shown in Table IIbelow. As can be seen, only Pluronic L-101 passed the Initial wetting,Rewetting, Storage Stability, Diesel Fuel Resistance, and the FlashPoint above 300° F. tests. It was totally unexpected that Pluronic L-101would bond so tenaciously to the pulverized uintaite, as evidenced bythe Rewetting test; the rewetting index for this surfactant was 1.01.Even when the Pluronic L-101 treated uintaite was mixed with water for24 hours and then dried, its rewettability was still excellent.

The surfactants tested include:

A=Pluronic L-101, a 10% ethylene oxide polyoxypropylene-polyoxyethyleneblock copolymer, MW TM 3800; BASF Wyandotte, New Jersey.

B=Morwit D-425; Petrochemical Co. Inc., Houston, Texas.

C=Daxad; W. R. Grace.

D=Reax 45A (Lignosulfonic acid); Westvaco, South Carolina.

E=Arsurf 906; Arjay Chem., Houston, Texas.

F=Arsurf 908; Arjay Chem., Houston, Texas.

G=Arsurf 910; Arjay Chem., Houston, Texas.

H=Arsurf 912; Arjay Chem., Houston, Texas.

I=Drilling Mud Surfactant; Sun Chemicals

J=Phase I; Sun Drill Fluids, Louisiana.

K TM Wyo Gils. Solv.; Wyo-Ben Company, Wyoming.

L TM Witcomul; Witco Corp., New York, New York.

M=Emcol 4500; Witco Corp, New York, New York.

N TM Witcomul; Witco Corp., New York, New York.

O=Coal Dust Retardent; Power Line Chem., Salt Lake City, Utah.

P=Cesco Coupler I; Cesco Corp., Lafayette, Louisiana.

Q=Cesco Coupler II; Cesco Corp., Lafayette, Louisiana.

R=Cesco Coupler II; Cesco Corp., Lafayette, Louisiana.

S=Pluronic L-81 a 10% ethylene oxide polyoxypropylene polyoxyethyleneblock copolymer, MW=2700;

BASF Wyandotte, New Jersey.

T=Pluronic L-61 a 10% ethylene oxide polyoxypropylene polyoxyethyleneblock copolymer, MW=2000;

BASF Wyandotte, New Jersey.

U=Rohm & Haas-30% solids, acrylic copolymer inn solvent; Rohm & Haas,Inc., Philadelphia, Pennsylvania.

V=Rohm & Haas-40% solids, acrylic copolymer in solvent; Rohm & Haas,Inc., Philadelphia, Pennsylvania.

W=Rohm & Haas-50% solids. acrylic copolymer in solvent; Rohm & Haas,Inc., Philadelphia, Pennsylvania.

                                      TABLE II    __________________________________________________________________________    Screening Tests for Drilling Mud Surfactants.sup.(1)             Dynamic Storage          Amt.             Wettability.sup.(2),                     Stability.sup.(3),                           Rewettability.sup.(4),    Surfactant          %  sec.    sec.  sec.     Flash Pt., (5), °F.    __________________________________________________________________________    None  -- Failed    A     3  7.8     4.8   7.9      460    B     5  Failed    C     5  Failed    D     5  Failed    E     3  *17.4    F     3  3.4     Failed    G     3  2.8     Failed    H     3  *11.0    I     3  Failed    J     3  Failed    K     3  Failed    L     3  7.2                    Failed    M     3  8.2                    Failed    N     3  *29.5                  Failed    O     3  *48.0    P     3  2.9     Failed         300    Q     3  2.9     *27.3 Failed   300    R     3  2.8     10.3  Failed   300    S     3  3.4     Failed         +400    T     3  3.1     Failed         +400    U     3  6.8     Failed    V     3  6.6     Failed    W     3  4.1     Failed    __________________________________________________________________________     .sup.(1) *Indicates failure.     .sup.(2) See Example 2.     .sup.(3) See Example 3.     .sup.(4) See Example 4.     .sup.(5) See Example 7.

EXAMPLE 10 Preparing an Additive Composition of this Invention

An additive composition of this invention was prepared in the laboratoryby combining 50% by weight Gilsonite® H.M. Pulverized (AmericanGilsonite Co.); 25% by weight Gilsonite® Selects 325 Pulverized(American Gilsonite Co.); and 25% by weight causticized lignite (Lenalkbrand purchased from Georesources, Williston, North Dakota) to a totalweight of 1500 grams. The three components were placed in a largeV-shaped blender equipped with a liquid dispersion bar. The blender anddispersion bar were turned on and 46.4 grams (3%) BASF Pluronic L-101was added through a liquid feed system. The blender was run for 30minutes to allow for even coating of the uintaites and lignite mixture.

EXAMPLE 11 Large Scale Additive Preparation

An additive composition of this invention was prepared on a large scale.Ten (10) tons high softening point (375° F.) uintaite was pre-blendedwith 5 tons low softening point uintaite (325° F). The unitaite was thenpassed through a fluid bed vibrating dryer to remove any moisture, andconveyed to a storage bin. A second storage bin was filled with 5 tonsof causticized lignite. Both bins had rotary feeders that simultaneouslyfed the components to a Pulvicron PC 38 (Bepex Corp.) pulverizer impactmill. RPM's of the feeders were adjusted to accomplish a three to oneblending ratio (75% uintaite to 25% causticized lignite). The mill wasrun at 1750 rpm and the air classifier was run at 975 rpm. AddingPluronic L-101 to the uintaite/lignite blend was done at the time of theblending and pulverization by pumping the Pluronic L-101 to thepulverizer where it was introduced into the mill. Temperatures in themill were about 110° F. during operation. Flow rates were adjusted toachieve good wettability of the treated uintaite, and varied accordingto ambient and mill temperatures, which effect the viscosity of thesurfactant and therefore its flow rate.

The mixture was milled to meet criteria A below; preferably criteria Bwas met. If sizing was too large, the large particles were recycledthrough the mill for further pulverization. This separation was done byair classification.

    ______________________________________    % Retained on Tyler Mesh Sieves (Cumulative)    Criteria            35 Mesh   65 Mesh   100 Mesh                                        200 Mesh    ______________________________________    A       Trace     1% max    3% max  20% max    B       0         0         1.0 max 5-10% max    ______________________________________

Tests of the product were conducted per Example 2 to assure that productpassed the weltability, test. The product dispersed in 2 seconds.

EXAMPLE 12 Additive Compatibility with Muds

An additive of the invention was tested in the four different types ofwater base drilling fluids shown below. The fluids selected werelime-KOH mud, KCl-polymer mud, seawater-polyanionic cellulose mud, andchrome lignosulfonate mud. All these fluids were unweighted. Six poundsper barrel of our additive was added to each of the fluids and mixedthoroughly. All samples were then allowed to stand overnight. In allcases the additives mixed easily and showed no sign of coalescence,i.e., there was no separation or clumping together of the uintaite.

    ______________________________________    Mud Makeup    ______________________________________    KCl-Polymer      Seawater-Polyanionic Cellulose    ______________________________________    1 bbl deionized water                     1 bbl deionized water    10.5 ppb KCl     14.7 gm sea salt    0.5 ppb PHPA     1 ppb lime    0.5 ppb polyanionic                     10 ppb attapulgite clay    cellulose        0.25 ppb PHPA    KOH to pH 9.0-9.5                     0.5 ppb polyanionic cellulose                     KOH to pH 9.0-9.5    ______________________________________    Chrome Lignosulfonate                     KOH-Lime    ______________________________________    1 bbl deionized water                     1 bbl deionized water    15 ppb bentonite clay                     15 ppb bentonite clay    6 ppb chrome lignosulfonate                     4 ppb KOH    3 ppb lignite    8 ppb lignite    2 ppb NaOH       8 ppb calcium lignosulfonate    pH 9.5-10.0      .25 ppb carboxymethyl                     cellulose                     6 ppb lime                     pH 11.5-12.5    ______________________________________     ppb = lbs/barrel     PHPA = partially hydrolyzed polyacrylamide

EXAMPLE 13 HTHP Core Test

A high temperature/high pressure (HTHP) fluid loss cell/Berea core testprovided data that could be used to discriminate between variousadditives. The procedure of this test is described in SPE Paper 17203 toDavis & Tooman, presented Feb. 28-Mar. 2, 1988, pp. 235-246. Additiveswere tested in a caustic water-based drilling mud. The tests indicatethat temperature and pressure influence the depth of intrusion ofdifferent softening point uintaites. It is desirable to obtain someintrusion, but not a deep depth of intrusion, i.e., about 1 mm ofintrusion. In addition, some intrusion of the material is necessary.(See page 243, Table #6, PE 17203.)

EXAMPLE 14 Downhole Simulation Test

Borehole stability was measured by the downhole simulation cell (DSC)described in SPE Paper 17202 to Simpson et al., presented Feb. 28-Mar.2, 1988, pp. 223-233, which is incorporated herein by reference. TableIII summarizes the results.

The DSC was used to test a series of uintaite blends to determinecompositions that provide borehole stability. Blends of differentSoftening point uintaites and blends of uintaite and lignite were used.The criteria for borehole stability was borehole enlargement experiencedin the test runs and measured on the shale core as described in SPEPaper 17202. The preferred result is a borehole size close to bit sizeand a low percentage of washout

The results of these tests are shown in Table III. The additives testedare described below. The low softening point uintaite was Gilsonite®brand Select 325, which had a softening point of 325° F. The highsoftening point uintaite 30 was Gilsonite® HM, which had a softeningpoint of 383° F. Causticized lignite was used. The additives were testedusing the muds and the conditions described in SPE Paper 17202. The bitsize for these tests was 1.25 inch.

A=A commercially available low softening point uintaite (˜325° F)product that was used with a commercially available coupler, i.e., auintaite-dispersing surfactant. This additive provided superiorstability at 125° F. compared to a high softening point uintaite.

B=A 50/50 blend of low and high softening point uintaites used with acommercially available coupler. This mixture exhibited comparableresults to low softening point uintaite at 125° F. At highertemperatures, this blend showed increasing washout.

C 50/50 blend of high softening point uintaite and lignite used with acommercially available coupler. This mixture provided excellentstability at 180° F., but showed significant washouts at 125° F. and250° F.

D 40/40/20 blend of high softening point uintaite, low softening pointuintaite and lignite, treated with Pluronic L-101 surfactant. Thismixture provided stability at 180° F, but stability deterioratedsignificantly at 250° F.

E=A combination of this invention, a 50/25/25 blend of high softeningpoint uintaite, low softening point uintaite and lignite, treated withPluronic L-101 surfactant. This additive provided superior stability atboth low and high temperatures (125° F. and 250° F.)

F=A commercial sulfonated asphalt. This additive showed some stabilityat 180° F.

=A commercially available surfactant-treated, high softening point (380°F.) uintaite additive. This additive showed some stability at 180° F.with 16% washout.

                  TABLE III    ______________________________________    Borehole Stability Test Results             (Fraction)             HM:Select:                       Test      Borehole Percent    Composition             Lignite   Temp. °F.                                 Size (inches)                                          Washout    ______________________________________    A         0:1:0    125       1.30     4    B        .5:.5:0   125       1.30     4    B        .5:.5:0   180       1.50     20    C        .5:0:.5   125       1.60     28    C        .5:0:.5   180       1.27     2    C        .5:0:.5   250       1.50     20    D        .4:.4:.2  180       1.30     4    D        .4:.4:.2  250       2.30     84    E        .5:.25:.25                       125       1.30     4    E        .5:.25:.25                       250       1.30     4    F        Sulfonated                       180       1.40     12             Asphalt    G         1:0:0    180       1.45     16    ______________________________________

These results clearly show that the combination of this invention,additive E, is superior to the other drilling mud additives tested,performing effectively over a wide temperature range. This additive issuperior at both low temperatures and high temperatures when compared toasphalts and additives containing a single softening point uintaite. Thecontinuing good performance of this additive depends on using the fightsurfactants, that is those with strong affinities for the unitaite, suchas Pluronic L-101.

EXAMPLE 15 Field Trial of the Additive of this Invention

A field trial of the additive of this invention was run on an offshorewell in the Gulf of Mexico. The field test was very successful with thewell reaching its total depth of 84430, with no problems. After settingsurface casing at 4500', the mud system was broken over to alignite/polymer mud containing 2 lbs/bbl additive. The mud used was alignite/polymer. No mixing or coalesing problems were observed whileadding the additive of this invention to the mud system. Additiveconcentrations were maintained at 2-2.5 lbs/bbl throughout the drillingof this hole. Mud weights ranged from 9.7 to 10.7 lbs/gallon. Hole angleaveraged 21° in this directional well and no excessive torque or dragwere experienced.

Caliper logs in the open hole interval 4500'-8400' showed hole washoutto average 16%. The sand/shale interval showed no excessive washoutwithin the open hole, except in the last 200 feet when salt wasencountered. Offset wells, which utilized commercial uintaite and blownasphalt products, experienced hole washouts of 30-40%. % Washout iscalculated by the following formula: ##EQU2## where D_(hole) is diameterof hole and D_(bit) is the diameter of the drill bit.

Results from this trial are shown in Table IV.

                  TABLE IV    ______________________________________    Field Trial Results.sup.(1)                   Our Additive                            Additive Z.sup.(2)    ______________________________________    Interval Used (ft.)                     4500-8400  4620-9080    Avg. Hole Angle  21° 50°    Bit Size (in.)   121/4"     97/8"    Mud Weight (lbs/gal)                     9.7-10.7    9.4-10.1    Additive Conc. (lbs/bbl)                     2.0-2.5    2.0-4.0    Total Amount of  6500       20,650    Additive Used (lbs.)    Avg. Hole Size from                     14.2       13.1    Caliper (in.)    % Washout        16         33    ______________________________________     .sup.(1) The well lithology was a mixture of sand and shale.     .sup.(2) Additive Z is a combination of two commercially available     additives containing uintarte, used sequentially. If recommended, an     emulsifier was added during addition.

As can be seen from this table, our invention provided well-borestability resulting in less washout than the offsetting well which usedcommercially available uintaite products.

EXAMPLE 16 FSCOT Analysis of Additives

Laboratory-prepared drilling fluid samples containing additives weresubjected to hydrocarbon extraction and FSCOT chromatographic analysisto determine if the additives might interfere with the geochemicalinterpretation of well data through misleading fluorescence data.Hydrocarbons in drilling mud can potentially invade any cores which maybe taken. Chromatographic analysis of hydrocarbon extracts of cores canusually distinguish mud additives from native oil, but field examinationof invaded cores can show a misleading fluorescence from the mudadditives Hydrocarbons from mud additives might also show up in coreanalysis retorts of invaded cores.

The FSCOT chromatograms of the solvent extract of a drilling mud samplecontaining our additive showed low levels of hydrocarbons all the wayout to the C-40 components. The heavy-end components (C-28 to C-38) showthe familiar FSCOT pattern of uintaite. Any surfactant in the sample isgenerally represented by the lighter hydrocarbons (C-8 to C-20) in thechromatogram.

The FSCOT analysis of our additives qualitatively showed low levels ofhydrocarbons (very few peaks over 8mV scale). Relative to the uintaitepeaks, the surfactant peaks from our additive were much lower than in acommercial uintaite mud tested in comparison. The chances of thesurfactant in this material causing problems with the geochemicalanalysis of cores should therefore be much less than with the commercialadditives.

Having described our invention as related to the specific embodimentslaid out above, it is our intention that the invention not be limited byany of the details of description, unless otherwise specified herein. Weintend that our invention be broadly construed within the spirit andscope set out in the following claims.

What is claimed is:
 1. A method of preparing a water-wettable drillingmud additive comprising the steps of:mixing together about 2 parts of ahigh softening point uintaite solid having a softening point of at least360° F., and about 1 part a low softening point uintaite solid having asoftening point of about 330° F. or lower; adding causticized ligniteand a strongly lipophilic surfactant.
 2. A method as described in claim.[.11.]. .Iadd.1.Iaddend., wherein said lignite is added whilepulverizing the uintaite solids and wherein said surfactant is added byspraying.
 3. A water-wettable drilling mud additive that stabilizes aborehole during well drilling, comprising a preblended stabilizingcombination of about 2 parts of a high softening point uintaite to about1 part of a low softening point uintaite, combined with causticizedlignite and a strongly lipophilic non-ionic surfactant which provides arewetting index of less than about 4 to the uintaites, wherein thesoftening point of said uintaites are about 40° F. apart or greater. 4.A water-wettable drilling mud additive comprising a mixture of:(a) 45 to55 percent of a high softening point uintaite having a softening.[.pint.]. .Iadd.point .Iaddend.above about 375° F.; (b) 20 to 30percent a low softening point uintaite having a softening point belowabout 330° F.; (c) 20 to 30 percent of causticized lignite; and (d) 2 to4 percent a strongly lipophilic non-ionic surfactant which provides arewetting index of less than about 4 to the uintaites.
 5. A drilling mudadditive as described in claim 4, wherein said lipophilic surfactantcomprises a block copolymer of ethylene oxide and propylene oxide, andprovides a rewetting index of less than about 2 to the uintaites.
 6. Adrilling mud additive .Iadd.for stabilizing boreholes during welldrilling.Iaddend., comprising:a pre-blended, borehole stabilizingmixture of a high softening point uintaite having a softening point ofat least 360° F., a low softening point uintaite having a softeningpoint of about 330° F. or lower, causticized lignite, and a surfactantthat provides the uintaites with a rewetting index of less than about 4,wherein the ratio of said high softening point uintaite to said lowsoftening point uintaite is about 2 to
 1. 7. A drilling mud additive asdescribed in claim 6, wherein said surfactant provides the uintaiteswith a rewetting index of less than about
 2. 8. A drilling mud additiveas described in claim 6, wherein said surfactant is a highly lipophilicnon-ionic surfactant comprising a block copolymer of ethylene oxide andpropylene oxide.
 9. A drilling mud additive as described in claim 6,wherein the weight ratio of said high softening point uintaite to saidlow softening point uintaite to said causticized lignite is about 2 toabout 1 to about
 1. 10. A drilling mud additive as described in claim 6,wherein said high softening point uintaite has a softening point aboveabout 375° F.
 11. A drilling mud additive as described in claim 10,wherein the softening points of the two uintaites are at least 40° F.apart.
 12. A drilling mud additive as described in claim 6, wherein saidlow softening point uintaite has a softening point of from 290 to 330°F.[.and said additive is storage stable.]..
 13. A drilling mud additiveas described in claim 12, wherein said high softening point uintaite hasa softening point above about 375° F.
 14. A water-wettable drilling mudadditive that stabilizes a borehole during well drilling, comprising apreblended stabilizing combination of a high softening point uintaite,having a softening point of at least 360° F., a low softening pointuintaite having a softening point of about 330° F. or lower, causticizedlignite, and a strongly lipophilic non-ionic surfactant which provides arewetting index of less than about 4 to the uintaites, wherein the ratioof said high softening point uintaite to said low softening pointuintaite is about 2 to
 1. 15. A water-wettable drilling mud additive asdescribed in claim 14 comprising about 2 parts by weight of said highsoftening point uintaite, about 1 part by weight of said low softeningpoint uintaite, and about 1 part by weight of said causticized lignite.16. A drilling mud additive as described in claim 14, wherein saidnon-ionic surfactant comprises a block copolymer of ethylene oxide andpropylene oxide, and provides a rewetting index of less than about 2 tothe uintaites.
 17. A drilling mud additive as described in claim 14,wherein the amount of said non-ionic surfactant is 1 to 5 wt. % of saidadditive.
 18. A drilling mud additive .[.ass.]. .Iadd.as.Iaddend.described in .[.claimed.]. .Iadd.claim .Iaddend.14.[.;.].wherein said high softening point uintaite has a softening point aboveabout 375° F.
 19. A drilling mud additive as described in claim 14,wherein the softening points of the uintaites are about 50° F. apart, orgreater.
 20. A drilling mud additive as described in claim 14, whereinsaid low softening point uintaite has a softening point of from 290° to330° F.[.and said additive is storage stable.]..
 21. A drilling mudadditive as described in claim 20, wherein said high softening pointuintaite has a softening point above about 375° F.
 22. A water baseddrilling fluid containing the additive of claim 14 or 4 or 6 or
 3. 23. Amethod of decreasing shale sloughing and borehole instability,comprising the step of:incorporating the additive of claim 14 or 4 or.[.5.]. .Iadd.6 .Iaddend.into a water-based drilling fluid at a rate ofabout 2 .[.roo.]. .Iadd.to .Iaddend.6 lbs. of additive per barrel ofdrilling fluid.
 24. A method of drilling a well, comprising the steps ofinserting a drill bit into the well and circulating a drilling mudcomprising the additive of claim 14 or 4 or
 6. 25. A method of drillinga well .[.las.]. .Iadd.as .Iaddend.described in claim 24, wherein thebottom hole temperature of said well ranges from ambient up to 400° F.26. A method of drilling a well as described in claim 24, wherein thebottom hole temperature of said well ranges from ambient to about 300°F. .Iadd.
 27. A method of preparing a water-wettable drilling mudadditive comprising the steps of:mixing together a high softening pointuintaite solid having a softening point of at least 360° F., and a lowsoftening point uintaite solid having a softening point of about 330° F.or lower; and adding causticized lignite and a surfactant effective todecrease the rewetting index of the uintaites, wherein the weight ratioof said uintaites to said causticized lignite is between about 3:1 toabout 4:1..Iaddend..Iadd.28. A method as described in claim 27, whereinsaid lignite and surfactant are added concurrently while pulverizingsaid uintaite solids..Iaddend..Iadd.29. A method as described in claim27, wherein said lignite is added while pulverizing the uintaite solidsand prior to the addition of the surfactant..Iaddend..Iadd.30. A methodas described in claim 27, wherein said surfactant is added prior to theaddition of said lignite..Iaddend..Iadd.31. A method as described inclaim 27, wherein said solids are pulverized such that no more thanabout 20% of said solids are greater than about 200mesh..Iaddend..Iadd.32. A water-wettable drilling mud additive thatstabilizes a borehole during well drilling, comprising a preblendedstabilizing combination of a high softening point uintaite and a lowsoftening point uintaite, combined with a causticized lignite and asurfactant effective to decrease the rewetting index of the uintaites,wherein the softening point of said uintaites are about 40° F. apart orgreater and wherein the weight ratio of uintaites to said causticizedlignite is about between about 3:1 to about 4:1. .Iaddend..Iadd.33. Anadditive as described in claim 32, wherein the additive stabilizesboreholes over a temperature range of at least 125° F to 250°F..Iaddend..Iadd.34. A drilling mud additive as described in claim 32,wherein said surfactant comprises a block copolymer of ethylene oxideand propylene oxide..Iaddend..Iadd.35. The drilling mud additive ofclaim 32, wherein said surfactant provides the uintaites a rewettingindex of less than about 4..Iaddend..Iadd.36. The drilling mud additiveof claim 35, wherein said surfactant provides the uintaites with arewetting index of less than about 2..Iaddend..Iadd.37. A drilling mudadditive for stabilizing boreholes during well drilling, comprising:apre-blended, borehole stabilizing mixture of a high softening pointuintaite having a softening point of at least 360° F., a low softeningpoint uintaite having a softening point of about 330° F. or lower,causticized lignite, and a surfactant effective to decrease therewetting index of the uintaites, wherein the weight ratio of uintaitesto said causticized lignite is between about 3:1 to about4:1..Iaddend..Iadd.38. A drilling mud additive as described in claim 37,wherein said surfactant provides the uintaites with a rewetting index ofless than about 4..Iaddend..Iadd.39. A drilling mud additive asdescribed in claim 38, wherein said surfactant provides the uintaiteswith a rewetting index of less than about
 2. .Iaddend..Iadd.40. Adrilling mud additive as described in claim 37, wherein said surfactantis a strongly lipophilic non-ionic surfactant comprising a blockcopolymer of ethylene oxide and propylene oxide..Iaddend..Iadd.41. Adrilling mud additive as described in claim 37, wherein said lowsoftening point uintaite has softening point of from 290° to 330°F..Iaddend..Iadd.42. A drilling mud additive as described in claim 41,wherein said high softening point uintaite has a softening point aboveabout 375° F..Iaddend..Iadd.43. A drilling mud additive as described inclaim 41, wherein the amount of said surfactant is 1 to 5 wt. % of saidadditive..Iaddend..Iadd.44. A drilling mud additive as described inclaim 37, wherein said high softening point uintaite has a softeningpoint above about 375° F..Iaddend..Iadd.45. An additive as described inclaim 37, wherein the additive stabilizes boreholes over a temperaturerange of at least 125° F to 250° F..Iaddend..Iadd.46. A method ofpreparing a water-wettable drilling mud additive comprising the stepsof:a) mixing together about a high softening point uintaite solid havinga softening point of at least 360° F., a low softening point uintaitesolid having a softening point of about 330° F. or lower; b) melting themixture of step a; c) dissolving or trapping a surfactant effective todecrease the rewetting index of the uintaites in the molten mixture ofstep b; d) solidifying the mixture of step c; e) pulverizing the mixtureof step d; and f) adding causticized lignite, wherein the weight ratioor uintaites to said causticized lignite is between about 3:1 to about4:1..Iaddend..Iadd.47. A water-wettable additive for water-baseddrilling fluids that stabilizes a borehole during well drilling,comprising a pre-blended stabilizing combination including causticizedlignite, a high softening point uintaite, an amount of low softeningpoint uintaite effective to stabilize boreholes over a temperature rangeof between about 125° F to about 250° F, and a surfactant effective todecrease the rewetting index of the uintaites..Iaddend..Iadd.48. Theadditive of claim 47, further including an intermediate softening pointuintaite..Iaddend..Iadd.49. The additive of claim 47, wherein saidsurfactant provides said uintaites a rewetting index of less than about4..Iaddend..Iadd.50. The additive of claim 47, wherein the weight ratioof said high softening point uintaite to said low softening pointuintaite is between about 1:1 and about 4:1..Iaddend..Iadd.51. Theadditive of claim 50, wherein said weight ratio is between about 3:1 andabout 4:1..Iaddend..Iadd.52. The additive of claim 47, wherein saidtemperature range is between about 125° F and 450° F..Iaddend..Iadd.53.The additive of claim 47, wherein said surfactant is stronglylipophilic..Iaddend..Iadd.54. A drilling mud additive for stabilizingboreholes during well drilling, comprising a pre-blended boreholestabilizing mixture of causticized lignite, a high softening pointuintaite, an amount of low softening point uintaite effective tostabilize boreholes over a temperature range of between about 125° F,and about 250° F, and a surfactant which is effective to decrease therewetting index of the uintaites..Iaddend..Iadd.55. The additive ofclaim 54, wherein said surfactant is stronglylipophilic..Iaddend..Iadd.56. The additive of claim 54, wherein saidtemperature range is between about 125° F and 450° F..Iaddend..Iadd.57.A method of preparing a water-wettable drilling mud additive forstabilizing boreholes during well drilling, comprising the steps ofmixing a high softening point uintaite with an amount of low softeningpoint uintaite effective to stabilize boreholes over a temperature rangeof between about 125° F and 250° F, and adding causticized lignite and asurfactant effective to decrease the rewetting index of theuintaites..Iaddend..Iadd.58. The method of claim 57, wherein saidsurfactant is a strongly lipophilic non-ionicsurfactant..Iaddend..Iadd.59. The method of claim 57, wherein saidtemperature range is between about 125° F and 450° F..Iaddend..Iadd.60.A water-based drilling fluid containing the additive of claim 32, or 37,or 47, or 54..Iaddend..Iadd.61. A method of decreasing shale sloughingand borehole instability, comprising the step of:incorporating theadditive of claim 32, or 37, or 47, or 54 into a water-based drillingfluid at a rate of about 2 to 6 lbs of additive per barrel of drillingfluid..Iaddend..Iadd.62. A method of drilling a well, comprising thesteps of inserting a drill bit into the well and circulating a drillingmud comprising the additive of claim 32, or 37, or 47 or54..Iaddend..Iadd.63. A method of drilling a well, comprising the stepsof inserting a drill bit into the well to form a bore-hole andcirculating a drilling mud into said bore-hole and through said wellduring said drilling, said drilling mud containing a water-wettableadditive for water-based drilling fluids that stabilizes a boreholeduring well drilling, said additive including a pre-blended stabilizingcombination including a high softening point uintaite, an amount of lowsoftening point uintaite effective to stabilize boreholes at atemperature above about 125° F, and a surfactant effective to decreasethe rewetting index of the uintaites, said additive being effective tosubstantially reduce sloughing shales and bore-hole erosion to therebyreduce bore-hole collapse, while increasing bore-holelubrication..Iaddend..Iadd.64. The method of claims 57 or 63, whereinthe softening points of said high softening point uintaite and said lowsoftening point uintaite are at least about 40° Fapart..Iaddend..Iadd.65. The method of claims 57 or 63, wherein saidhigh softening point uintaite has a softening point of at least 360° Fand said low softening point uintaite has s softening point of about330° F or lower..Iaddend..Iadd.66. The method of claims 57 or 63,wherein said low softening point uintaite has a softening point ofbetween about 290° F and about 330° F..Iaddend.